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– degradation rates for xylan, glucomannan
And HexA 253
– Gustavson and Al-Dajani 252
– hardwood prehydrolysis 329–343
Kinetics
– carbohydrate degradation 215–216
– cellulose chain scissions 217
– chain scissions 685–687
– kraft pulping 185–229
– oxygen delignification 671–687
Knot screens, secondary (screening and
cleaning equipment) 604–605
Knots, selective removal 593
Kozeny see Carman–Kozeny relationship
“kraft”, word origin 5
Kraft chemical recovery 980
– future 992–994
Kraft cooking 733
– active chemicals 114–116, 221, 988
– aliphatic hydroxyl groups elimination 261
– Bjerrum diagram 118
– carboxylic groups enrichment 261
– chemicals 221
– delignification phases 184
– diffusion mass transfer 123, 137–150
– experiments 225
Index
– extractives fractions 182–183
– fiber bundle 60
– lignin mass balance of Eucalyptus globulus
– liquors 113–121
– modified see modified kraft cooking
– PHK see PHK process
– pine see pine
– prehydrolysis see PHK process
– pretreatment 129–130
– process chemistry 229–325
– Purdue model 198–199
Kraft cooking kinetics
– alkali and hydrogen sulfide consumption
220–221
– concentration of cooking chemicals
217–220
– delignification kinetics 211–215
– numerical solution of cooking chemical
concentration equations 228–229
– parameters 221–227
– structure 211–229
– validation and application 223–227
Kraft cooking kinetics models
– carbohydrate degradation 193–198
– delignification 189–198
– H-factor concept 189–191
– kraft cooking kinetics 199–211
– pseudo first-principle 198–199
– pulping selectivity 197–198
– review 188–211
Kraft cooking mass transfer, diffusion 123,
137–150
– impregnation 122–123
– penetration 122, 129, 132–137
Kraft cooking pretreatment
– digester evacuation 129
– steaming 129–132
Kraft process 12, 17
– development 6
– dissolving pulp 1024
– prehydrolysis- 345–365
– uniform pulping reactions 1047
– see also kraft pulping
Kraft pulp 1010
– beating resistance 1011
– carbohydrate composition 470
– conventional see conventional kraft pulp
– emission levels 1005
– global fiber production 9
– hardwoods 723
– R-values 1015
– sheets 800
– softwoods see softwood kraft pulp
Kraft pulping
– black liquor 111–112
– carbohydrates reactions 174–181
– chemistry 163–185
– chromophore reactions 172
– extractives 181–183
– formaldehyde 169
– glucomannan 180
– green liquor 112
– kinetics 185–229
– levopimaric acid 183
– liquor composition 476
– low-lignin pulp production 323
– multistage 325–365
– nucleophiles addition 167
– processes 111–391
– reactions overview 183–184
– selectivity plot see selectivity plot
– tall oil soap 112
– technology and equipment 366–391
– toxic compounds 112
– transition metals 859
– white liquor 111
– xylan 179
– see also kraft process, see also lignin
kraft recovery boiler 980–985
– emission limits 1003
– schematic 981
– see also kraft chemical recovery
Kraft residual lignin, linkage frequencies 638
Kramfors process 465
Kubelka-Munk theory 610, 1279
Kvaerner compact press 557
Kvaerner double atmospheric diffuser 553
Kvaerner Dual mixer 620
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