|
Mannuronic acid Alluronic acid Altruronic acid
CHO
HO H
HO H
H OH
H OH
COOH
Quot;_ __ ______ _ _ _________ ____
__)
1____ ___ 5_ __
__#__
____ _._ 1____ __
3___ __ __ ____ ___ __,__ _ _______ _____ ___ __ _____ _____ _ _ _____'
_____ _______ ___ _________ _ ___ ___ _______ _____ 3 __________ _____ __ ___
___ ________ _ __ ____ _____ _ _ _________ _ ___ __ ____ _ ___ _ _____'
_____ __ _____ ___ __ _ _____ __ ______)__ __ ___ ___ _________ ____ __'
_____ __ _______ __ ______: _____ ___ ________ _ _ ___ __ __ ___ __
____ __ _ ____ ______ ___ _____ _ __ ____ __ ___ __ $_ -._ ___
_____ _______ ___ ____ _:B$_ ___ _ _ __________ _________ _ ____ ______
____________ _______
____
___ _________ ____
3_____ ____ __ _ ___________ _ ___ ______ _____ __ _ _ ___ _ ___
__ ___ _ ___ __ __ ____ (_ ___ __ __ ___ ___ __ ______ __ __ ____ __ __
________ _ ___ ___ _ ___ __ _,__ __________ (_______ ___ __ "___&__ _
___ _____ _____ ____ ___ _ ___ ________ ___,__ ___ ___ __ ______ _ _ '
_ __ (_________ ______ _______ ____ _ _____ _ __ ___ _ _____ _ _)____
_____ _)____ *_@__
O
R
(H,R)
RNH2 N
R
(H,R)
+ R
Carbonyl Schiff base
-H2O
-_!__ ___ _____ __ _ ___ ______
_____ _____ ____ ______ _____ ___ ___ 3LC _ ___ "_ _ __ _ _ _____ _'
_ ___ ___ __ ____ ____ ___ _____ _______ _)____ *_+__ ____ _ ____ __ ___'
___ _ ___ __ __ _____
O
O
RNH2 N
O
+ R
Lactone Schiff base
-H2O
-_!__ ___ $___ __ _ ___ ____ % _ ____ & _ __ _________ __ __ _ __________ ____ __'_
_____ _____ __ __ ___ ___ ______ ____ ____ ___ ___ ___ ___ ___ ___ ___'
__ _ ___ _ _ __ _____________ _ ____ ____ ___ ___ __ __ __ _______ ____ &__
______ _ ___ _ _ ___ ___ __ __ _____ ___ __ _______ __ ____ _____ /6+1_
3 ______ __ ____ __ _ ___________ _ ___ ___ ____'_______ "____ ___ __'
_ _______ ____ ___
__#____ _ ____ ____ _9_(9)
___ ____ ______ __ _ ______ _______ _ _ ________&___ ___ _______ __ ___'
____ _ _ ________ _ ____ __ _____ _ ___ __ _______ _____ ___ _____ _ _
_"_______ ____ _ __________ ___ ________ ____ _____ _ __ "_____ __ ___
______ _ _______ _____ __ _________) _ _____ ___ __ _ ___ ___ __ ___
_______ __ ____ ______ __ __ __ ___ _______ __ G_ /661_
___ ____ ______ __ _______ __ ___ ______ _ _____ _ _____ ____ ___
3_+C_ ________ __ _ ___ ______ _ _ 3_)C0 __ @55 _ _ ___ _ _____ _______
___ __ _"_ ___ _ _ _ 3__ _ _ ___ _ __ __ _,____'________ _______ ___ 3_+C
_________ __ ___ ____ __ ___ _____ _______D _____ _______ ___ _______ ___ 3_+C
__ ____ ___ __ _ ___"___ _____ ___ ________ _____ _ _______ _____________
___)
_ ________ ____ __________
__#____ -,_: _!.,__,_ ___!,
:__%0 ______ ___ __ _ ____ "_ __ ____ _ _____ _)____ *_*_ K _ ___
_____ __ __ _"___ _ ___ _______ _____ __ _____
O
R
(H,R)
CH
R
(H,R)
+ 8NaBH4 + 18H2O 32 OH + 2Na2B4O7 + 4NaOH
-_!__ ___ $____ __ _ ________ ______ __ _____ __________ ()*+),-_
) ____ _ _ ________ ____ __ _ _ ______ __ _____ _ ____ ___ __ __ ____
__ ___________ __ __ ___ _ ____ ___ ___ __ ______ ___ _)____ *_0__
2NaBH4 8H2 2B(OH)3 Na2SO4 H2SO4 + 6H + 2+ O +
-_!__ ___._______ __ _ _ ____ _____ __________ _ ________ ____
___ __ ___ _ ____ ___ __ ____ __ ____ ________ _ _________
__#____ 4.,__;___ ___!, _9'
____ ___ __ _________ __ _ _ ___ _ ________ _____&____ ___ ___ __ __ ___
_ __ _____& ___ _ _____ _)____ *_<_
O
R
(H,R)
H2N NH2 N
R
(H,R)
NH2
Buffer
H2SO4
+
-_!__ __) _____ __ ___ ________ __ _ _____"_____
(____ _____ _ ____ _____&___ ___ ________ ___ __ __ _____& __ __ ____ ___
__ ______ ___ ___ ___ ________ _____&___ __ __________ __________
__#____ <___ ___!, _9_
(_ ________ ____ "_ _____ ____ _ ____ __ ____ ____ _____ _ _____ _
)____ *_6_
O
R
(H,R)
NH2OH.HCl N
R
(H,R)
+ OH
Carbonyl Oxime
+H2O +HCl
-_!__ __9 / __ ____ __ _ ________ _______
___9
___ _________ ____
___ ________ _ _ ___ __ __ ___ __ __ _____ __ _ ___ __ ___ _
____ _ __ ___ __________ _ __ ___________ ___ _____ _ ____ ___ __ ___
_ ______ ____
__#___# 5____,/% ___!, __3
Amp;____ ____ _____ ____ ___ __ __ ___ _
____ ___ ___ __ __ ____ ___ ______ _ __________ _ _____ ___ _ ___ ______
_ ___ ____ _ __ ______ __________ __ ___ ____ ___ _____ _ ___ __ ___ _
__ ___ ___ ____ _ _ ____ ____ ___ _"____ _ ____ __ ________ __________
__#___) _.__!.,___ ___!,
%___ ___ ______ __ _____ _____ _ ___ __ __ ___ _ _ __ ___ _______
_)____ *_=__
O
R
(H,R)
HCN
R OH
(H,R)
+
Carbonyl
Cyano hydrin
C N
-_!__ ___ _____ __ _ __________ (*_-_
___ ______ _ __________ _ _ ___ __ ___ __ __________ ___ ___ ____ ___ _'
_____
__#___* 1_ _______ _.___
$M_____ __ __ /=+1 ________ _ _____ ________ ____ _ _ ____&___ ___ ____
_____ _ _______ __ ______ __ ____ ____& _'>'___ "__ ___ /+'_+'___'
_ "_'___ "__'___ "_1'_____ _33C(__ ___ ________ ___ _____ _ _ ____ __
__ __ __)____ *_E_
(_ ____ _______ ______ __ __ _____ __ _______________'______ _ ____
_GB(F__3_ _ _____ ___ _____ __ __ ___ __ ____ ___ ___ ____________ __
_ ___ __ -____ __'________ _ __ ___ ______ _8_3_ _________ ____ _ __
)(_)' ____ ____ ____ __________ ___ __ ______ ______ __ ___ _____ _
_________ _ ____ ______ __________ _ __ __ _______ ____ ___ ___ __ _'
____ _ ___ _________ _ ____ ______ _____ ___
____
_ ________ ____ __________
O
R
(H,R)
+
Carbonyl
H2N
O
Rf
N
R
(H,R)
O Rf
O-substituted oxime
- H2O
N
O
O
O
O
NH2
Rf
Spacer
Florophore
-_!__ __" _ ____ _ _________ ____ __ _________ ____ __ ___+ __/0_
__#__
____ _._ 1____ __
3___ "_ __ ___ ___ _______ _______ _ _ __ _"____ __ _ _ ____ ___ ___ __ ___
__ _ ___ __ ___ ___ _______ (_____ __ ___ __ _________ __ "_____ _ _____ __
______ _______ ______ ___ ___ _______ _ ___ "__ __ ___ __ ___ ____ ___'
_ _ _ _ ___ ___ __ ______ _____ _ ____ _____ __ ___ __ ____ _ _______ _
___ ______ ___ _ _ ____,_ _ ____
Quot;__ _____ __ _ ___ __ ___ ___ __ _ ___ _ ____ __ ____ _
___ ___ __ __________ ______ _____ _ _'_"_____ _____ __ ____
)____ *_>__
R
O
OH
+ K+A- R
O
OK
+ H2O + H3O+ + A-
-_!__ __'!__ _ ______ ____ __ _ _____ ___ ___ ____
___ ____ ____ #N ____ __ _ _ ___ ____ ________ _ ___ "__ __ ___ ____ _
___ _____'_ _ (A_ ___ ________ _ _ ___ "__ __ ___ ___ ____ __ _____'
_____ __ ___ _______ __ _______ _ __ _______ _ _ ___ ____ ____ _______ #N_
(_ __ ___ _______ _ ____ __ _______ _ _ ___________ ___ "_ __ ___ ____
____ *_@__ ___ __ __ ____ __ _________&__ _ _,_ ____:_%3C*_ (_ _'
_"_____ ____ __ __ __ _____ ___ __ ____ _____ ___ ___ __ ____ ____ __
_______ __ _______ ____ ________ ___ ________ ___ "_ ______
___"
__! "_ __ _____ __#_____ $___ ____ __%
6___ ___ 1_ ____ __ __ __ _____ __ _ _____ ___ _______
_______ %________ _ ________ _________$_&
3__3%*3CC_+ (_____ =*
3__3%*3CC_+ =0
O__3%*3CC_+ O__3%*3CC_+ =<
:_3 N:_%3C*:_%3C*' _______ _ =6_==
:_3 N:_C%:_C%' _______ _ =E __ _____ ________
=> _ ____ ________
3_____ __ __ G__' _______ _ E5
B_______ ___ G__' _______ _ E@
__9
______ _ % _.___;___ _ $_ ______ ____&
B___ ___ _ __ __ _______ _ ___ _ ____ __ ____ ______ ______ _
___ ____ _____ _ ___ _ _____ _______ ___ G_ _ _ ____ ____ _ ___ _ '
_____ _ __ __ __ _____ ___ G_ __ ________ _ _ _______ ___ ______ ____'
___ ___ ____ ________ ______,___ ___ ________ (__ _ _____ _______
______ _ ____ _ _________ _____ ____ __ ___________ __ _ __________ _ ___'
__ __ __ __ __ __ K___ *_6_
___ G_ __ ________ __ _ _____ _ ______ __ _ __ ____ ___ ___ "_______ _____'
____ _ ____)___ _.'0_6_0__ _ __ ___ _______ __&_ _ ___ _ ____ __ __ __ ___
_______ __ ___ _ ____ ____ ___ ___ _ _____ ____ _ _______ _ _______
0,02
0,04
0,06
0,08
0,1
0,12
0,14
0,16
0,18
0,2
0,2
0,4
0,6
0,8
Wi
i
i
W di
Degree of polymerization
Molecular mass
Number
Average
Weight
Average
Differential
Distribution
Integral
Distribution
1___ __9._ ___ __ ___ __ _ _________ ____ &_____ ______ _ _______"_ __'_
___'
___3 _ ________ ____ __________
_ ______ __ ________ ____ ___ _____ _ __ _______ __ _ _________ _____ _____'
_ __ _______ __ _ ___ __ B __ ____ __ ____ __ _______ ____ _ _ ___ _ ____
_____ ___ ____ __ ___ __ _______ ____ __ ____ ___ _____ _ __ __ ___ ______ _
___ __________ _ _____ __
__)__
- _2____ _ _ _____ __
_ ____ _ _________ ___ __&__ _ _____ ___ _ _____ _____ ____ _____ __ ___'
_ ____ 3__ __ ___ __ ____ ___ __ _____ ____ __ _ ______ _ ___ __ _ ___'
_&__ __ _ ___ _____ _ _____ __ ________&___ __ _ _ _"____ ______ _____ _ _
__ __ ________ _ _______ _______ _ _____ _ ____ ____ ___________ _ ______'
____ _________________
(______ _ ___ _ __ __ _ ____ __ _ _____ _ _ __ __ __ _________ __
____ *_+_ __ __ _ _____ ____ _____ ____ _ __ _ __ ____ ___"__ _______
__ __ ___ _ _______ __ ____ 3 ___ _____ _________ _ ______ __ _ _______
__ ___ _ ___ __ _ __ __ _ ____ ___ ___ _________ _ _______ ____ ___
______ H____ ___I __ __________ _ ____ ______ ____ __ _________ (_
_____ _ _____ ___ _,____ ___ ___ _ _ __ _ ___ _____ ____ ___ _________ _
_ ___ ____ ___ ___ ________)__ _________ _ __ _ __ ______ ____ _____ ___ __'
_ __ _____ __ _______ __ ___ ___ ________ _ _ __ ____ __ __ __ _ ______ __
___ _______ _ "_____ _ _____ ____________ ___ ____ _ _______ _"___ _____'
____ __ ___ ___ ___ __ __ __ _______ _ _ _"____ _____ _ _ _______ _________
___ __ ____ ____ ___ __ __ _______ __ _ ___"___ _ _____
6___ ___ 02_____ ______ _ __ __ _________ %___ __ _____ __ _ __________
*__ _. _ _ ____ _ ____+_
CP(B
_)____&__Q_
________
3 ____ "___'___ ___ G___ ___ _D ____ ___ _ __________
____ _&_ ______ ____ __ ______ _ "____D
_______ ______ _ _ ___________ __ __
__ ____ _
3-2:2
_32G_
D _____ ___ ___ _______
___ _____&___ _
3(GCP2:
_3(GCP__
Quot;___ __ _______
_______
2___ ______ ___ _______ ________
D __ _ ____ ____ _____ _ _____
__'_ ___ _
GB(F__3 G______________'______
_ ____
B _____ ____ ____ __ ____ _ ____
________ __ __ _ ___ __
:B:C _'_ ___ ___ _' "___
_______
__! "_ __ _____ __#_____ $___ ____ __%
__)____ _8<=*_
_____'_____' _____ _'____ "____ /3__:%*_01_C%_+_*%+C _)____&__Q_ _________
__ ________ __ ____ ____ ____ _ ____ __ +5? ___ ___ ___ "___&___ ___ _'
___ ________ ___ _ ____ __ ___ "___ __ _________ (___________ ______ ______'
_____ 3_C __ ____ ___ __ +5? ___ ___ /E+1_ 3___ ________ ___ ____ ___ _____
___ _ _____ _ _ _ 3__ _________ ' ___"_ ____ _ ____ __ _ _______ ____ _
_________ ___ G_ _ __ ___ (________ ____ _ ___ ____ _ _______ __ O_'
______ /E*1_
__)____ _8__ _"_
___ ____ H___I __ ____ __ _ __ ______ _____ _ _ ____'_______'_______'_ _'
__ _ _3G2__ _ _______ ___ _ _ ___ __ 3__C%_+ __ ___________ __ _ _ ____ __'
____ _ ___ _ __ ___ ___ ___:_C%_ ___ ___ ____ ____ "___ __ ____ ___ __
_______ ________
__)____ >_ _ -,_ 6_______ $_?__& _")
(_ _,____ _ ___ _ _ __ _ _ ____ ________ ___" __ ________ __ ______
K_3*_6%+C _ _ _ ___ _ _ _ ____ ________ ___ ______:_C% ___ _ ___ ____'
____ _ _ ____ _ _ ______&___ _ _ ___ _ ___ _ /E61_
__)__
__2____ *2_____ @____ _ _ ______ ____ __, >_,__ _ _ ____ ___.
(____ __ ____ _ _ _ _____ ____ ___ _____ __ ____ __ __ _______ ______ _
___ _ ____ ____ _ _ _ _ _____ _ _ __ __ _"_____ ____ _ __ _ _____'
____ ____ _ __ __ ________ ____ __ ______ __ ________ ___ ___ _ ___
_______ _ _ _ ____ __ _____ _______ % ______ _ __ ____ __ ___ _ _ ______
_________ _ ___ ______ _ _ ____ __ ___ _____ ______ ____ __ ___ _ _ ___ _
H ___I__ K _ _"_____ ____ _________ __ _ _____ ___ _ ___ __ _________
__ _ ____ _ ___Q_ _ ____ _____ 3 __________ ____ ____ _ _ __ _ _ ___ ___
______ H______I ___ _ _____ ___ __ _____ _ ____ ____ _____ _ ___ _________
______ _ ___ ____ __ ______ _____ __ /______ ________ __ _______ __ 2__ _@_1_
__ _ _
_
_+
_
_ _
__
_ _
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____
_ ________ ____ __________
C____ _______ ____ __ ___ _________ _ _ ____ _______ __ _______ _ _ _____
____ ___ __ _ __ ___ ______ _ ___ _ ____ ______ ____ ____ *_*__
6___ ___.____ ____ ______ _ _________ ____ ___ ______ _
_______"_ __ &.3'+ __ ____ __ _____ __ _____
6.__ _
___
?___!___
____ _
*2_____ ______ A___!_ *2_____ _% *___._____ __!,
8_____
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_____
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______@
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___________ _
C__ ___
______
_______
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_____ _ _____
___
_ _ ___ +
_
___ _
_____ _________
)__________ _
__________
_______________
&'_______ + __ _ ____*
_
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_ _ _________ ______ ___ _________ _____ _ ________ ______ __________
%_____' ____ ________ ____ _____ _____ ____ ___' ____ ________ _B_N@R B___
(_____ ____ __________ _ ___________ __ ___ _ _____ _____'____"_ __ ____
__ &__ _ _ _ _ ________ ______ ___ ________ ____ _________ _ ___________
/2__ _+_1;
_ _
__
__ _ @ _+_
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__! "_ __ _____ __#_____ $___ ____ __%
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B___ __ _______ _ _ _ ___ _ ________ ___ _ ____ ______ _ _ __ _ ___
____ ________ _ _ _ ___ ___ __ _ ___ __&_ _ ___ ____ ___ ________ _ _
_____ _ ____ _______ ___ ______ __ _____ 2_______ __ _______ __ 2__ _*__ __ _
_____ _ _ _ ____ _____ __ ___ ____' ________ __ _;
_________ _
_ _ ________
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__5
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_*_
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___ ______ __ _______ _______ _ &__ ________ __ _ ____ __ _______ ____ __
__ _"____ _______ _ _ ____ ____ _ ___ _ ____ ___ ____ ____ __ ____ _ _
_ ____ ____ ___________ _ ___ _____ __ ____ *_0_
6___ ___ ______ _ __ ____ _ __ _____ _________ _____
___!, ___ ___D
______2_
-_______ __ ____. _____,
C__ ___ _ C__ __ ________
_____ _________
)__'____ P'___ _________
)__'____ _____ _ _________
_ ______ ________ __ ___ ______ _ _ __ _______
____ _ ____
-____________ _)__________ _ ______ ___ _______ _ _______
3 ________ _ ________ _ ______ ___ ______
G______ _ _ G______ _ ______
)_&_'_"___ _ __ ___ ______
___'________ _ __ ___ _______
_ $______ _ ____ __ _ _________ __
.__ ____ _.__ ____ ______ __ &__ ______
__)____ <_ ___
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_____ _ _ /2__ _0_1;
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_ _
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_ ________ ____ __________
_____ (+D (* L __ __ ___ _____ _____ ________ _ __ __ ________ ___
B_L _ ____ ____ _ _ ___ _______ _________
___ __ __ ________ __ ________ __ _ ___ __ _ _ ____ _____ _ ____ _ '
____'______ __ ____ ________ ____ _____ _____ ___________ ____ __ ____
_______ B __ ____ __ ____ __ __________ ____ _____ ___ _ _ _ ____'______
__ ____ ______ _____ _______ ____ _____ ____ ____ __ ____ __ _____ ____ _ _
____ __ __ __ _ ___ ___ ___ _________ __ _____ __ _ ____ __
______ _ __ __ ___________ __ _____ _ ______
___ _ ____ ____ __ _______ __ _ ___ ______ __ __ _________ ____ __
____ __ _ ______ ____ ______ __ ____ __ ________ _ 5_ _______ __ ___ _"'
____ ___ _ _ _____ _______ __ ______ ________ ___ ________ _ _____ _
)____ *_@*_ _ _________ __ __ __ __ K___ *_=_
Mn
c [g/cm3]
Π /c [mol/g]
A2
C1 c2 c3 c4 c5
1___ ___ 4_____ __ _ __________ _ _ ____ _ _________
0 5 ______ ____ ______ __+ __+ __+ _ __ 5 ______ __ ____
Δp
Quot; ___ _______ _ __ ______ ____ _ ________ __
________ ______ ___ __ 5 ________ _______ &5 ____ _
________'_
____
__! "_ __ _____ __#_____ $___ ____ __%
C__ __ ________ ___ __ ________ ______ __ _____ _ ____'________ ___'
______ ____ _________ __ __!____ _______ ________ ___ _ ___ _ ___ _ '
_____ ___________ (_ ___ _ ____ _ ____ _______ ___ ___ ___ _________ ___
________ __ ___ _ ____ ______ _________ ___ _________ __ ________ _______
___ __ _______ _____ ___ _ ___ __ __ _________ ___ _________ _ _ __
_________ _ _ _________ __ __ ________ __ __ __ _________ __ K___ *_E_
_ _____ ____ ___ ____ _______ __ __ ___ _____ __________ __ _ ________
_ ____ ' __ __ _______
(___________ ___ __ __ ________ ___ __ __________ ________ __ ___ _____
_ ___ _ _________ ___ ________ _ _ ___ _ _________ __ __ _ _ ___ _ _____ __ _ _'
__ __ _ ___ __ __ _________ _ /2__ _<_1;
_ _ ___________ _ _________ _<_
: _____ ___ _________ __ ___ _ ________ __ __________ __ __ _______ ____ __
___ __ ________ ________ _ ___ ___________ __!________.___ ___ ______'
____ ___ _______ _ ________ _ ____ ____ _ __ _________ _ _ ________ _ _ _'
___ _______ ___ __ _ _ _______ _ _ ______ _ __ ______ ________ __ ___
__)____ -_________ ___!,_
)________ ____ __ _________ ___ _______ __ ____ __ ________ ________ __ ___
____ ___ ___ _ _____ ___ _ ___ _ _______ _ ___ __ ______ ____ __ _ _
_____ P'_____ _ _________ _____ __ __ _ _ _____ ____ __ ___ _ __ ________
__ __ _____ ____ __ ____ ______ _____ %____ __ __ _ _ _____ _ _____ _ ___ '
___ _ _____ __ 3_' ___ K_' ________ ___"__D __________ __ __ __ _ _'
___ ________&__ ___ ____ ___ __ __ _____ _ ____ _ _ ____________ ___ ___'
______ ___________ ___ __________ ___ _____________
Sample
Polarizer detector
Laser
Light trap
Θ
1___ __' 3______ _ ________ __ ______ ___ ____ ___ &_______ __ __ __ _____'_
._____ ____ _________ __ ________ __ __ _________ _ _____ _ K___ *_>_ ___
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___)
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____ K _ ____ ____ __ ____ __ ___ ___ _____ ____'____ ______ _ ___________ _
___ _ _ ____________ _____ _____
___ _______ _ ___&__ _______ ____ __ ________ __ ___ ___ _ ____ __ _ '
___ __ ___ ________ ____ __ _______ __ _ __ _ ______ ____ ______ ___ _____
__ _ _ __& ___ _____ ___ _______ ____ _________ __ __ ____ __ _ _____ _ _ ___
_________ _____ __ (___________ _ ______ _ __"__ _____ __ ___ ________ ___
_____ ___ ____ __ ____ __ _________ ______
___ _______ _________ _ ____ ________ __ _ ______ _________ ______ _
_$_ L ________F ________ _______ _;
_ ___ ________ _ _ ___ _ ___ _ ___D
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_____ ___ ____" _ _______ _ ________ ___F L ___ ___ _ A __ _____F_D
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_ ___ _________ ____ ____
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_________ __ _____'________ ____________ K _ _______ _______ __ __&_ _ ___
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______ ___ ________ _____
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____ _ __ __ ________ /___ 2__ _0_1_
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__ _______ 2___ _6_ ___ _=__ ___ ________ ____ ___ __ _"____ ____ _ &__ _'
_______ __ __ __ __ _ &__ ______ _________ _____ ____ __ _ ____ _ __ __
_____ _ _ '___ O___'_ _ ____ K___ *_@5__ ____ __ _ __ '_______ __ __!___ _
_ ___ _____'_______ __ _____ _ $ L ________ ___ O___' ______ O ___ __ _ '
___ ___________ _ ____ _ __'___ ___ ____ __ _____ ________ _ ____'____ ____
___ _______ _ ____ _ _ _ ______
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______ ______
K_ _ ___ O___ _____ _____ ______ __________ __ __ _______;
_ B ____ ____ _______ ________ B_
_ $_____ _ ______ _ _&'________)&
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C1
C2
C3
C4 c5
C0
Θ= 15.
Θ= 45.
Θ= 45.
Θ= 90.
Θ= 120.
Θ= 135.
Θ= 0.
A2
S
v
K c
R
Z c sin
Θ
1/M ⋅ + w
1___ ___3 6!11____ __ __ ______ __ _ ___ ____ ____ __ __
_ _____ ___ _____'_ ____ __ _______ __ ___ _ ___ __ ___ _________ __ _
_____ __ ____ _____ _ ____ _____ _"____ ___ _ __ _ _ _ ______ _ ____ ____ _ ___'
__ _________ ____ _______ ___ ____
___ ____'_________ ____ _ __ ______ ____ ___ ___ __ _____ __ ___ ___ ____ _ _
_ ____ ____ ___ _______ ______ ___ _____ _ __ __ ___ _____ _ _ ___ _ ______
_ _"_____ __ _____ ______ _ ___ _ __________ (____'_________ _________
___ __ __ ____ __ _ ________ _____ _ _ __&_'_"___ _ __ ___ ______ ____)_'
__ _ *_6_<_+_
____
_ ________ ____ __________
__)__
@___ ___. __________
__)____ - ___ _ @___ ___. __ _ ______ _ ____ ______ _!___ _____!
_ _____ ___ _______ ___ _ ___ __ _ _____ ____ _____ ______ ______ _
_ ____'______ __ _____ ____ _ _____ ___ ____ ____ ___ _ ___ __
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