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– demand 881
– equilibrium 881
– oxidation capacity 613
– oxidation equivalents (OXE) 264
– post-treatment 883
– pulp bleaching 880
Perforation plates, patterns 53
Permanganate demand, hot acid hydrolysis
permanganate number 1228–1229
Permeability 513
– as function of fiber concentration 514
peroxide bleaching 1132, 1134–1135
– catalyzed 877
– ozonation 1038
– pressurized 866–867
Peroxide solutions, stablity in water 863
Peroxide stage, residence time 865
Peroxide-supported extraction stages,
Temperature effect 865
PGW see pressure groundwood
PH
– acid sulfite cooking liquor analysis 433
– oxygen delignification 704–705
– pine delignification 473
– profile 728
– pulp washing parameter 533–534
– Rauma three-stage sulfite cook 471
– sorbed sodium 520
– spruce pulp yield and acetyl content 474
– sulfite pulping processes 393
– temporal development in AS/AQ pine
Pulping 479
pH effect, ozone bleaching 811–812
PH fall during bleaching, oxidation
Processes 863
Phase transformation model, kappa
Numbers 684
Phases, cellulose I 26
Phenolate anions 703
Phenolic compounds
– absorbance spectra 58
– hardwoods 38
– softwoods 37
Phenolic coupling, hydroxyl radical adducts of
Aromatic structures 654
Phenolic extractives, topochemical
distribution 61–63
Phenolic hydroxyl
– content in lignin samples 636
– content in residual lignin 263
– relative reactivity 635
Phenolic hydroxyl groups
– bleaching 848
– in lignin fractions 173
Phenolic lignin subunits
– carbohydrate degradation 795
– chemistry 164
– chromophore formation 172
– structure 164
Phenolic phenylcoumaran structures 411
Phenolic phenylcoumarans, neutral sulfite
Pulping reactions 413
Phenolic pinoresinol structures 410
– neutral sulfite pulping reactions 414
Phenolic polymer, lignin 31
Phenolic structures, hydroperoxide
Formation 652
Phenols
– in condensation reactions 424–425
– ionization 703
Phenoxyl radical
– chlorine bleaching 746
– formation by oxygen or by hydroxyl radical
Phenylcoumaran structures, phenolic 411
Phenylpropane a-carbonyl-b-arylether
Structures, sulfonation 412
Phenylpropane building blocks, lignin 32
Phenylpropanols 858
Phenylpropanones 858
Phenylpropene unit 2, HOMO- and electron
Density distribution 633
PHK process 11, 345–365, 816
– development 7
– dissolving pulp 1024
– influence of process conditions 351–358
– influence of wood species 358–365
– lignin and xylan removal rate 348
– see also prehydrolysis
PHK pulp
– purification effidency 942
– selectivity 838
Index 1331
Phosphate ion, ozone decomposition,
Promotor 789
Photochemical oxidation, lignin models 655
Photodegradation, a-carbonyl groupcontaining
Lignin model compounds 655
Photometric methods, metal ions
Determination 1222
Photometry, operating principle 1221
Photosensitized degradation, loblolly pine
(Pinus taeda) 656
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Ozone bleaching 793, 798 | | | Physical properties, hydrogen peroxide |