|
Dakin-like reaction 858
Darcy’s law 132, 147, 513
DCM, extractive 234, 330, 342, 360, 365,
450–451, 961, 1013, 1030, 1061
Deacetylation, glucomannan in superbatch
Process 280
Debarker, Nicholson A2 78
debarking 71–80
– methods 72–80
Debarking resistance, seasonal development
Debarking state, wood quality 1075
Debris passage ratio, in relation to screening
Efficiency 590
Debye–Huckel–Onsager equation 142
Decayed wood, waste generation 105
Deciduous woods, structure 50
Decomposition
– chlorine dioxide 737
– homolytic 651
– hydrogen peroxide 854–856
– metal ion-catalyzed 791
Decreasing-permeability model 517
Defiberization, lignin compounds 1123
Defibration
– conditions 1102
– single fibers 1083
Deflocculation, fibers 562
Degradation
– carbohydrates 794–798, 859
– cellulose 1056–1059
– cellulose/hemicellulose under alkaline
Conditions 175
– end products 956
– lignin 790–794
– pathways for glucosone and xylosone endgroups
– pentoses and hexoses 420
– products 446
– wood components 437–449
Degradation acids, relative frequencies
(oxidative degradation) 637
dehydration, carbohydrates 419–421
deinking 1165, 1174–1175
Deliberation 1113
– single fibers 1083
delignification 16–17, 61, 79, 110–112,
158–162, 705–706, 828–829
– activation energy literature data 201–202
– alkali charge 700
– alternative bleaching methods 887
– as function of pH 473
– beechwood acid sulfite cooking 437
– behaviour 834
– bleaching 809, 887
– blowtank 826
– brightness dependence 870
– carbohydrate reactions 657
– chain scissions number 260
– chlorine dioxide 752, 755
– degree of 697, 717
– dioxygen-alkali delignification processes
657–666
– DualoxTM system 730
– effect of carry-over 717
– effect of impregnation on delgnification
uniformity 158–162
– effect of increasing chlorine dioxide 762
– electrochemical 887
– Eucalyptus saligna prehydrolysis kraft pulp
With oxygen delignification 260
– extent 1228–1229
– final pH 705
– hemicellulose degradation in initial phase
– H-factor 259
– high-shear mixers 826
– industrial 688, 695
– kappa number 258, 678, 684
– kinetics 211–215, 671–685
– kraft cooking 184, 189, 211
– lignin solubilization 714
– low-consistency ozone bleaching 809
– mass transfer rate 697
– medium-consistency ozone delignification
System 826
– NaOH-charge 730
– offgas 826
Index 1305
– oxygen see oxygen delignification
– OxyTrac system 730
– ozone 777–849
– pH 473
– phases in kraft cooking 184
– pine 473
– predicted by selected model of kraft cooking
Kinetics 223
– pressure 730
– process equipment 731
– profiles within handmade chip 160
– relation to oxygen delignification
Efficiency 259
– retention time 730
– selectivity 363, 809, 815
– temperature 730
– two-stage 473, 730
– washing 826
– see also kappa number
Delignification chemistry 632
– (di)oxygen and derivatives 641–649
Delignification efficiency
– Eucalyptus saligna prehydrolysis kraft pulp
With oxygen delignification 260
– temperature effect 813
Delignification rate 802
– equation 681
– prehydrolysis effect in prehydrolysis-kraft
Process for Eucalyptus saligna 351
Delignification reactions, selectivity 838
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