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The degree of sulfonation may be calculated as:
Degree of sulfonation _
Sulfur _S_
Methoxy groups _-OCH3_
The specific energy consumption affects the property of mechanical pulps, and
is at least 2 MWh t–1 o.d. pulp for strongly fibrillated TMP and CTMP pulps from
Spruce. The processing of pine chips increases specific energy consumption by
The data in Fig. 4.26 illustrates how strength properties are dependent
Upon on specific energy consumption. The so-called F-value in Fig. 4.26 is a
Mechanical Pulping Processes
Strength value that combines tensile strength and tear strength, according to the
following equation:
F-value = 10. breaking length (km) + 0.1. tear strength (mJ m–1)
Fig. 4.26 F-value (strength value) depending on specific
energy consumption (according to Suttinger [22]).
The refiner process is carried out mostly as a one- or two-stage process. In twostage
Processes, the main part of energy is used in the first stage. The defibration
Concentration in the refining zone of the first refining stage is of major importance
for the quality of the mechanical pulp, and should range from 20 to 45%,
with 25% as an optimal value.
As for grinding, spruce wood is also the most suitable raw material for refining,
Though pine or hardwood with a low density may also be used. Again as with
Grinding, a high wood moisture is needed for refining. The size distribution of
The wood chips should constitute only a small part of fines fraction, and they
Must be of a certain degree of purity. Sand and other minerals are abrasive for the
Refiner plates; hence, the wood chips are often washed before defibration.
4.2.3
Machines and Aggregates for Mechanical Pulping by Refining
Disc refiners of different construction are widely used in the refining procedure,
Mostly as single-disc or double-disc variants. Other commercially available
Designs include several types of large-capacity refiners, such as the Twin concept
Or conical disc concept.
Single-disc refiners have one fixed and one rotating disc (Fig. 4.27), while
Double-disc refiners have two counter-rotating discs (Fig. 4.28). Two types of largecapacity
TMP refiners are available: the Twin concept was introduced by Sprout
(today Andritz), and is characterized by two parallel single-disc refiner gaps (i.e.,
Three discs, with the center disc rotating and the outer discs fixed; see Fig. 4.29).
Refiner Processes
Somewhat later, Sunds Defibrator (today Metso) developed the RGP CD (= conical
Disc) system. Conical-disc refiners have a single-disc refining gap followed by
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Fig. 4.25 Exchange of hydroxyl groups by sulfonate groups | | | A conical refining gap inside one refiner housing (Fig. 4.30). |