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5. Calculate equivalent mass of KMnO4 (M=158 g/mol) for RedOx titration in acidic medium:
31,6 g/g-eq | Answer:____________________ | |
79,0 g/g-eq | ||
52,7 g/g-eq | ||
158 g/g-eq |
6. To propose the reagent for the separation of cations:
Mg2+, Pb2+ ↓ |
| ||
Solution:_______ Cation | Sediment:_______ (chemical formula) |
7. Determine correspondence of titration methods and their indicators:
A B C D | Neutralization Complexonometry Iodometry Permanganatometry | Diphenylammine Litmus Starch Eriochrome black T | Answer: А - _______; В - _______; С - _______; D - _______. |
8. This figure demonstrates the curve of titration of _______ (weak or strong) _________ (acid or base) by _________ (weak or strong)____________ (acid or base).
9. Calculate ionic power µ (or I) of solution, contained 0,1 M K2SO3 in 1 L.
1. | 0,50 | Answer:____________________ |
2. | 0,30 | |
3. | 0,10 | |
4. | 0,09 |
10. Note relative specific reagent of Fe3+ cation
Sodium Bismuthate NaBiO3Zinc-Uranyl-Acetate | Answer:___________________ | |
Potassium ferrocyanide K3[Fe(CN)6] | ||
Potassium ferricyanide K4 [Fe(CN)6] | ||
Ammonium Hydrophosphate (NH4)2HPO4. |
11. To propose the buffer mixture, using proposed reactants (possible more than one true variant)
NH2Cl, Na2HPO4; NaH2PO4 | Answer:_____________________________________________________________________________ | |
NH2OH; KOH | ||
HCl, H3PO4 |
12. Titr concentration is shown:
Quantity of soluble substance in grams per 1 L of solution; | Answer:______ | |
Quantity of soluble substance in grams per 1 grams of solution; | ||
Quantity of soluble substance in grams per 1 mL of solution; | ||
Quantity of soluble substance in mol per 100 mL of solution. |
13. Apparatus, presented at picture, is used for identification of anions:
Answer:___________________ |
15. To write reaction of Co3+ Chloride and excess of ammonia thiocyanate in molecular form (coordinative number of Co3+ is 6) and to calculate the sum of coefficients in this reaction (remember, that absence of coefficient before formula means figure 1):
__________ + ___ ____________ → _____________________ + __ ______________
Sum of coefficients: ______
16. Calculate gravimetric factor f for determination of Ca2+ content in CaCl2·6H2O (M=219,08 g/mol) in the form of precipitate Ca2P2O7 (M=254,10 g/mol):
1,7380; | Answer:___________________ | |
0,8622; | ||
1,1599; | ||
0,5799. |
17. What is dentation of Tetrasodium EDTA:
Mono dental; | Answer:___________________ | |
Bi dental; | ||
Tri dental; | ||
Tetra dental. |
18. Calculate mass of H3PO4 (M=98,00 g/mol), dissolved in 500 mL of solution, if for titration of 10 mL of this acid it was used 10 mL of 0,01 N NaOH):
Solution: _________________________________________________________________________
_________________________________________________________________________________
Answer:_________________
19. Calculate solubility (in g/L) of Fe(OH)3 at pH=4 (SP=4·10-38; M=98,22 g/mol)
Solution: _________________________________________________________________________
_________________________________________________________________________________
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Determine correspondence of titration methods and their secondary standards (working solutions). | | | Answer:_________________ |