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Acid processing generally requires pulps of higher purity as compared to alkaline
Processes. Acetate pulps are high-purity pulps containing hemicelluloses in
an amount less than 1.5% and no detectable residual lignin. Experimental findings
Strongly suggest that even very small amounts of certain hemicellulose fractions
Play an important role in the formation of haze and color of cellulose triand
Diacetate solutions. Glucomannan from both acid sulfite and prehydrolysis
Kraft (PHK) pulps is a major source for diacetate haze, false viscosity, and poor
filtration [17]. False or anomalous viscosity determines production capacity, and is
Defined as the percent increase in dope viscosity compared to that of a dope prepared
From cotton linters diacetate of the same composition and intrinsic viscosity.
The effect of the pulp mannan content on false viscosity and filterability of a diacetate
Solution in acetone is illustrated in Fig. 11.6.
Glucomannan is very detrimental to diacetate filterability (obtained from the filtration
of 18% diacetate acetone dope through a cotton fabric media at 275 kPa),
Whether it comes from acid sulfite, PHK or conventional kraft pulp. Even small
0 1 2 3
False Viscosity Effect [%]
Filtration Value [g/cm2]
Mannan content [%]
Acid Sulfite PHK Kraft
Fig. 11.6 Effect of mannan content in various pulps on diacetate
filterability and false viscosity [17,19]. Pulp acetylation
according to the high-catalyst process using 14% sulfuric acid
Catalyst based on initial amount of cellulose. Diacetate dope
consists of 18% acetate, 1.35% water, and 80.65% acetone.
Dissolving Grade Pulp
Amounts of glucomannan seem to deteriorate filtration of the dope. It is assumed
That glucomannan is competing against cellulose for acetylation, leaving swollen
Fiber fragments in the solution. Xylan causes only a moderate drop in filtration in
the range below 2%, but this is the major contributor to acetate color and thermal
Instability. Diacetate color is measured by determining the yellowness coefficient
[Cy = (T640 – T440)/T640] of a 12% diacetate dispersion in a mixed solvent of dichloromethane
And methanol. The xylan originating fromPHK pulps causes more intense
Yellowing than that present in acid sulfite pulps (Fig. 11.7). This behavior has been
Explained by the lower content of uronic acid side chains of the kraft xylan compared
to sulfite xylan which, on acetylation, produces hazy solutions [20]. Kraft cooking conditions
Favor the removal of 4-O-methylglucuronic acid substituents from xylan,
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In the steeping lye inhibits cellulose degradation during ageing due to the | | | Whereas xylan retains its branched structure during acid sulfite pulping. |