Студопедия
Случайная страница | ТОМ-1 | ТОМ-2 | ТОМ-3
АвтомобилиАстрономияБиологияГеографияДом и садДругие языкиДругоеИнформатика
ИсторияКультураЛитератураЛогикаМатематикаМедицинаМеталлургияМеханика
ОбразованиеОхрана трудаПедагогикаПолитикаПравоПсихологияРелигияРиторика
СоциологияСпортСтроительствоТехнологияТуризмФизикаФилософияФинансы
ХимияЧерчениеЭкологияЭкономикаЭлектроника

Is still under investigation.

Читайте также:
  1. AMD Athlon (Thunderbird) 800
  2. B). Open the brackets. c). Put questions to the underlined words.
  3. Comparison to Sulfonation Reactions under Conditions of Neutral Sulfite Pulping
  4. Exercise 11. Put questions to the subjects. Then put special questions to the underlined words.
  5. Exercise 13. Put questions to the underlined words.
  6. EXERCISE 2 Read the text, understand its contents and give a short review of this text.
  7. EXERCISE 4 Read the text and understand its contents.

Acid processing generally requires pulps of higher purity as compared to alkaline

Processes. Acetate pulps are high-purity pulps containing hemicelluloses in

an amount less than 1.5% and no detectable residual lignin. Experimental findings

Strongly suggest that even very small amounts of certain hemicellulose fractions

Play an important role in the formation of haze and color of cellulose triand

Diacetate solutions. Glucomannan from both acid sulfite and prehydrolysis

Kraft (PHK) pulps is a major source for diacetate haze, false viscosity, and poor

filtration [17]. False or anomalous viscosity determines production capacity, and is

Defined as the percent increase in dope viscosity compared to that of a dope prepared

From cotton linters diacetate of the same composition and intrinsic viscosity.

The effect of the pulp mannan content on false viscosity and filterability of a diacetate

Solution in acetone is illustrated in Fig. 11.6.

Glucomannan is very detrimental to diacetate filterability (obtained from the filtration

of 18% diacetate acetone dope through a cotton fabric media at 275 kPa),

Whether it comes from acid sulfite, PHK or conventional kraft pulp. Even small

0 1 2 3

False Viscosity Effect [%]

Filtration Value [g/cm2]

Mannan content [%]

Acid Sulfite PHK Kraft

Fig. 11.6 Effect of mannan content in various pulps on diacetate

filterability and false viscosity [17,19]. Pulp acetylation

according to the high-catalyst process using 14% sulfuric acid

Catalyst based on initial amount of cellulose. Diacetate dope

consists of 18% acetate, 1.35% water, and 80.65% acetone.

Dissolving Grade Pulp

Amounts of glucomannan seem to deteriorate filtration of the dope. It is assumed

That glucomannan is competing against cellulose for acetylation, leaving swollen

Fiber fragments in the solution. Xylan causes only a moderate drop in filtration in

the range below 2%, but this is the major contributor to acetate color and thermal

Instability. Diacetate color is measured by determining the yellowness coefficient

[Cy = (T640 – T440)/T640] of a 12% diacetate dispersion in a mixed solvent of dichloromethane

And methanol. The xylan originating fromPHK pulps causes more intense

Yellowing than that present in acid sulfite pulps (Fig. 11.7). This behavior has been

Explained by the lower content of uronic acid side chains of the kraft xylan compared

to sulfite xylan which, on acetylation, produces hazy solutions [20]. Kraft cooking conditions

Favor the removal of 4-O-methylglucuronic acid substituents from xylan,


Дата добавления: 2015-10-21; просмотров: 96 | Нарушение авторских прав


Читайте в этой же книге: Be expected when high dosages of, for example, ozone, or other bleaching chemicals | Is rather unstable in acid sulfite pulping, and this results in a low (hemicellulose) | Groups, depending on the amount and their distribution along the polysaccharide | Beech Sulfite Beech Kraft Eucalyptus Kraft | From rather high molecular-weight cellulose and very low molecular-weight hemicellulose | Fiber length below 0.2 mm, indicating the presence of large amounts of fines derived | As resins or inorganic compounds can adversely affect the filterability of viscose, | Is an important characteristic of dissolving pulps. Finally, the qualitative and | In the past, the latest forecasts reveal a slight change in this trend (see Chapter | Lyocell |
<== предыдущая страница | следующая страница ==>
In the steeping lye inhibits cellulose degradation during ageing due to the| Whereas xylan retains its branched structure during acid sulfite pulping.

mybiblioteka.su - 2015-2024 год. (0.005 сек.)