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For students all specialities



INDIVIDUAL WORK-14

For students all specialities

MODUL 2

 

The number of elements in the period is determined by:

a

Valency of elements

b

Number of filled up atomic orbitals

c

Orbital quantum number

d

Number of energy levels

f

Structure of an external quantum level

 

 

Among the given elements the greatest value of energy of an electron affinity has:

a

Carbon

b

Aluminium

c

Sulfur

d

Oxygen

f

Fluorine

 

 

Among the given elements electron jump up is most characteristic for:

a

Chromium

b

Calcium

c

Plumbum

d

Copper

f

Scandium

 

 

Among the given ions a similar to ion Na+ electronic shell is:

a

Ca2+

b

Mg2+

c

H+

d

K+

f

Li+

 

 

Bromine has larger oxidizing properties, than iodine, because:

a

Radius of atom of bromine is greater, than radius of atom of an iodine

b

Oxidizing properties of iodine is greater, than oxidizing properties of bromine

c

Radius of atom of iodine is greater, than radius of atom of bromine

d

Electron affinity of atom of bromine is greater, than electron affinity of atom of iodine

f

Electron affinity of atom of iodine is greater, than electron affinity of atom of bromine

 

 

At the decomposition of 25 g of a carbonate of twovalent metal was liberated 5,6 l carbon dioxide under normal conditions. The formula of the salt looks like:

a

SrCO3

b

CaCO3

c

MgCO3

d

BeCO3

f

BaCO3

 

 

Molecular orbitals are bonding if:

a

Density of electronic clouds of atoms, which form a molecule, are more then density of an electronic cloud of molecular wave function

b

Density of an electronic cloud in internuclear space is increased

c

Density of an electronic cloud in internuclear space decreases

d

Density of an electronic cloud in internuclear space does not change

 

Find the charge of a complex ion, charge, covalency and coordination number of the central atom in a hexaammine chromium (ІІІ) chloride, and also sum of coefficients in the equation of reaction of exchange of this salt solution with silver nitrate solution:

a

2+, 2+, 6, 6, 7

b

3+, 3+, 6, 6, 4

c

2+, 2+, 6, 6, 8

d

3+, 3+, 6, 6, 8

f

3+, 3+, 5, 5, 8

 

 

Find concentration of molecules NH3 which are formed according the first step of dissociation (first instability constant is К1 = 4×10–5) in 0,01 M solution of hexaamminecobalt (ІІІ) chloride, if concentration of the complex ion [Co(NH3)6]3+ at its dissociation practically does not change:

a

mol/l

b

mol/l

c

0,01 mol/l

d

mol/l

f

4×10–5×0,01 mol/l

 

 

Value for the reaction

H2(g)+ I2(g) = 2HI(g),

if react= –114,12 kJ/mol; react= 21,54 J/mol×К, is equal to:

a

–115,09 kJ/mol

b

–120,54 kJ/mol

c

–118,29 kJ/mol

d

–116,33 kJ/mol

f

–113,75 kJ/mol

 

 

A reaction runs according the equation

А2 + В2 = 2АВ.

The initial concentration of substance A is equal 0,8 mol/l, and substance B is 1mol/l. After some time the concentration of substance A has been decreased down to 0,5 mol/l. Find thus the concentration of substance В:

a

0,75 mol/l

b

0,3 mol/l

c

0,5 mol/l

d

0,2 mol/l

f

0,7 mol/l

 

 

The equilibrium constant of homogeneous reaction

2Н2S + 3O2=2Н2O + 2SO2

is equal 1. The equilibrium concentrations were: [H2S] =2 mol/l; [O2] = 4 mol/l; [H2O] = 4 mol/l. Find the equilibrium concentration of sulfur oxide:

a

2 mol/l

b

6 mol/l

c

4 mol/l

d

3 mol/l

f

5 mol/l

 


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